
The
primary nutritive value of kalo
is derived from the Starch that is stored in cells
of the corm (stem). 
Each cell has many Starch Bodies (Amyloplasts).
Each of these has many tiny Starch Grains.
The Starch Grains are liberated when the cells are subjected to small amounts of pressure. They would certainly be liberated during poi pounding.
The small size of the Starch Grains makes them easier to digest.